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Sodium Chlorite

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Sodium chlorite is an efficient stoichiometric oxidant in Sharpless asymmetric dihydroxylation. The conversion of styrene was achieved twice as fast as in the established Sharpless K3[Fe(CN)6] dihydroxylation. Eight olefins were dihydroxylated to corresponding vicinal diols with yields and ees as good as those reported in the literature for other similar processes.
M. H. Junttila, O. E. O. Hormi, J. Org. Chem., 2004, 69, 4816-4820.