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Triphenylphosphite

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A dichlorodioxomolybdenum(VI)-catalyzed oxotransfer allows a chemoselective deoxygenation of sulfoxides to sulfides in the presence of P(OPh)3 as the stoichiometric reductant.
R. Sanz, J. Escribano, R. Aguado, M. R. Pedrosa, F. J. Arnáiz, Synthesis, 2004, 1629-1632.