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Synthesis of 1,2-diketones

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Corey-Seebach Reaction


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1,3-Diols undergo smooth oxidative cleavage of the C-C bond in the presence of 2-iodoxybenzoic acid (IBX) affording 1,2-diketones in excellent yields under mild conditions.
J. S. Yadav, S. K. Biswas, R. Srinivas, Synthesis, 2006, 4237-4241.