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Synthesis of vinyl fluorides
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Monofluorovinyl tosylate is practical vinyl fluoride building block to couple
with various arylboronic acids in the presence of a palladium catalyst. A high
stereoselectivity in the synthesis of 2-aryl-1-fluoroethene derivatives was
achieved. This approach is also applicable to the synthesis of
2,2-diaryl-1-fluoroethenes in good yields.
H. Zhang, C.-B. Zhou, Q.-Y. Chen, J.-C. Xiao, R. Hong, Org. Lett., 2011,
13, 560-563.
