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C-H Bond Formation

Reactions


Decarboxylations, Decarbonylations


Dehalogenations and other Reductive Cleavages


Deoxygenations


Deoxygenations


Desilylations


Desulfurization


Synthesis of 1,4-cyclohexadienes


Reduction of aromatic compounds


Reduction of alkenes


Reduction of alkynes


Reduction of α,β-unsaturated compounds


Reduction of epoxides


Reduction of carboxyl compounds


Reduction of esters


Reduction of amides


Recent Literature


The preparation of alkenyl halides of any length from inexpensive starting reagents is reported. Standard organic transformations were used to prepare straight-chain α-olefin halides in excellent overall yields with no detectable olefin isomerization and full recovery of any unreacted starting material.
T. W. Baughman, J. C. Sworen, K. B. Wagener, Tetrahedron, 2004, 60, 10943-10948.