Categories: C=N Bond Formation >
Synthesis of imidates (imino ethers)
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Recent Literature
A mild, one-pot cyanoimidation of aldehydes using cyanamide as a nitrogen source
and NBS as an oxidant was achieved in high yields without the addition of a
catalyst. Subsequently, the substituted N-cyanobenimidate products may
also undergo a cyclization reaction to give 1,2,4-triazole derivatives in high
yields.
P. Yin, W.-B. Ma, Y. Chen, W.-C. Huang, Y. Deng, L. He, Org. Lett., 2009,
11, 5482-5485.
