Synthesis of oximes

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Recent Literature

In the presence of zinc oxide and without any additional organic solvents, Beckmann rearrangement of several ketones and aldehydes were performed in good yields.
H. Sharghi, M. Hosseini, Synthesis, 2002, 1057-1059.

A new synthesis of enamides from ketones involves a phosphine-mediated reductive acylation of oximes. The resulting enamides are isolated in good yields and excellent purity.
H. Zhao, C. P. Vandenbossche, S. G. Koenig, S. P. Singh, R. P. Bakale, Org. Lett., 2008, 10, 505-507.

J. P. Waldo, R. C. Larock, Org. Lett., 2005, 7, 5203-5205.

With a simple two-step procedure involving substitution with readily available TsNHOTBS and subsequent treatment with CsF, a range of oximes were prepared from the corresponding alcohols, alkyl halides, or alkyl sulfonates without using external oxidants.
K. Kitahara, T. Toma, J. Shimokawa, T. Fukuyama, Org. Lett., 2008, 10, 2259-2261.

The reaction of N-alkylhydroxylamines and aqueous hydroxylamine with monosubstituted allenes gives nitrones and oximes, respectively, in good yields. DFT calculations support a proposed concerted, five-membered Cope-type hydroamination process, and calculated transition state energies are in excellent agreement with experimental observations.
J. Moran, J. Y. Pfeiffer, S. I. Gorelsky, A. M. Beauchemin, Org. Lett., 2009, 11, 1895-1898.

A number of new reactions of IBX with heteroatom-containing substrates were discovered and their utility was demonstrated. IBX was used for the generation of imines from secondary amines in notably high yields, for the oxidative aromatization of nitrogen heterocycles and for the cleavage of dithianes.
K. C. Nicolaou, C. J. N. Mathison, T. Montagnon, Angew. Chem., 2003, 115, 4211-4216.

A convenient, environmentally friendly method for the synthesis of optically active aldoximes and nitriles starting from chiral nitroalkanes was developed.
C. Czekelius, E. M. Carreira, Angew. Chem. Int. Ed., 2005, 44, 612-615.