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N-Chlorinations

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N-Chlorination of various amides, carbamates and lactams with inexpensive and stable calcium hypochlorite on moist alumina proceeds smoothly and efficiently. Excellent results were also observed for the N-chlorination of protected amino acid esters with a cyclopropane moiety.
O. V. Larionov, S. I. Kozhushkov, A. de Meijere, Synthesis, 2003, 1916-1919.