N=S Bond Formation
Recent Literature
The synthesis of N-cyanosulfilimines can readily be achieved by reaction
of the corresponding sulfides with cyanogen amine in the presence of a base and
NBS or I2 as halogenating agents. Oxidation followed by decyanation
affords synthetically useful sulfoximines.
O. García Mancheño, O. Bistri, C. Bolm, Org. Lett., 2007,
9, 3809-3811.
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Sulfoximines, sulfilimines, sulfinimides, sulfonimidates and sulfonimidamides - the chiral sulfur connection |
