New Abstracts
Abstracts of articles in the field of organic synthesis,
published in the most highly regarded organic chemistry journals
Bonus
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Bonus (only available today)
Synthesis of Polysubstituted Furan Frameworks via [3 + 2] Annulation of N-Enoxyimides
with Chelated Alkynes Initiated by Rh(III)-Catalyzed C-H Activation
M. Wu, Y. Wang, J. Zhou, T. Wang, H. Gao, Z. Zhou, W. Yi, Org. Lett., 2023, 25,
2394-2399.
Synthetic and Computational Studies on RhIII-Catalyzed Redox-Neutral Cascade
of Carbenoid Functionalization and Dephosphonylative Annulation
S. Bera, P. Mondal, D. Sarkar, V. B. Pathi, S. Pakrashy, A. Datta, B. Banerji, J. Org. Chem., 2021, 86,
7069-7077.
Catalyst-Free Regioselective N2 Arylation of 1,2,3-Triazoles Using Diaryl
Iodonium Salts
S. Roshandel, M. J. Lunn, G. Rasul, D. S. M. Ravinson, S. C. Suri, G. K. S.
Prakash,
Org. Lett., 2019, 21, 6255-6258.
Abstracts
Asymmetric Cascade Carbonylation/Annulation of Benzyl Bromides, CO, and
Vinyl Benzoxazinanones Enabled by Pd/Chiral Lewis-Base Relay Catalysis
W.-W. Ding, Y. Zhou, Z.-Y. Han, L.-Z. Gong, J. Org. Chem., 2023, 88,
5187-5193.
Silyl Cyanopalladate-Catalyzed Friedel-Crafts-Type Cyclization Affording
3-Aryloxindole Derivatives
H. Ece, Y. Tange, T. Yurino, T. Ohkuma, Synlett, 2021,
32,
935-939.
Reductive C-O, C-N, and C-S Cleavage by a Zirconium Catalyzed
Hydrometalation/β-Elimination Approach
C. Matt, F. Kölblin, J. Streuff,
Org. Lett., 2019, 21, 6909-6913.
Sulfur-Arylation of Sulfenamides via Chan-Lam Coupling with Boronic Acids:
Access to High Oxidation State Sulfur Pharmacophores
N. S. Greenwood, J. A. Ellman, Org. Lett., 2023, 25,
2830-2834.
Carbamoyl Anion Addition to Azirines
M. J. Kerner, C. A. Kuttruff, M. Chevliakov, F. G. Buono, D. A. Gao, M.
Krawiec, C. A. Busacca, C. H. Senanayake, P. Wipf, J. T. Reeves, Org. Lett., 2021, 23,
4396-4399.
Preparation of Organic Nitrates from Aryldiazoacetates and Fe(NO3)3·9H2O
S. Thurow, A. A. G. Fernandes, Y. Quevedo-Acosta, M. F. de Oliveira, M. G. de
Oliveira, G. D. Jurberg,
Org. Lett., 2019, 21, 6909-6913.
Palladium-Catalyzed Reductive Formylation of Aryl Iodides with CO2 under
Mild Conditions
D. Li, L. Wei, W. Xiong, H. Jiang, C. Qi, J. Org. Chem., 2023, 88,
5231-5237.
Synthesis of Pyrroles via Consecutive 6π-Electrocyclization/Ring-Contraction
of Sulfilimines
F.-L. Haut, N. J. Feichtinger, I. Plangger, L. A. Wein, M. Müller, T.-N.
Streit, K. Wurst, M. Podewitz, T. Magauer, J. Am. Chem. Soc.,
2021, 143, 9002-9008.
Hydrogen-Bonding-Assisted α-F Elimination from Cu-CF3 for in Situ Generation
of R3N·HF Reagents: Reaction Design and Applications
S.-L. Zhang, J.-J. Dong,
Org. Lett., 2019, 21, 6893-6896.
Structural and Thermal Characterization of Halogenated Azidopyridines:
Under-Reported Synthons for Medicinal Chemistry
M. D. Mandler, A. P. Degnan, S. Zhang, D. Aulakh, K. Georges, B. Sandhu, A.
Sarjeant, Y. Zhu, S. C. Traeger, P. T. Cheng, B. A. Ellsworth, A. Regueiro-Ren, Org. Lett., 2022,
24,
799-803.
Metal-, Photocatalyst-, and Light-Free Minisci C-H Acetylation of N-Heteroarenes
with Vinyl Ethers
J. Dong, J. Liu, H. Song, Y. Liu, Q. Wang, Org. Lett., 2021, 23,
4374-4378.
Rh(III)-Catalyzed Coupling of N-Chloroimines with
α-Diazo-α-phosphonoacetates for the Synthesis of 2H-Isoindoles
B. Qi, L. Li, Q. Wang, W. Zhang, L. Fang, J. Zhu,
Org. Lett., 2019, 21, 6860-6863.
Photochemical Decarboxylative Formylation of Indoles with Aqueous Glyoxylic
Acid
V. Dinesh, R. Nagarajan, Synlett, 2023,
34,
855-857.
Merging Imidazolidines with a Trifluoromethylated Tetrasubstituted Carbon
through Tungsten Catalyzed 1,3-Dipolar Cycloaddition
Z. Chen, Y. Zhou, T. Hu, H.-Y. Xiong, G. Zhang, J. Org. Chem., 2021, 86,
7552-7562.
Synthesis of Z-Enamides through Heterogeneous Gold-Catalyzed
Stereoselective Hydrogenation of Ynamides
L. Lin, X. Zeng, B. Xu, J. Org. Chem., 2019,
84, 11240-11246.
Elemental Sulfur-Mediated Transformation of Carboxylic Acids to Acyl
Fluorides by Electrophilic Fluorinating Reagent, Selectfluor
E. M. Mahmoud, S. Mori, Y. Sumii, N. Shibata, Org. Lett., 2023, 25,
2810-2814.
Pd-Catalyzed Triple-Fold C(sp2)-H Activation with Enaminones and Alkenes for
Pyrrole Synthesis via Hydrogen Evolution
L. Fu, Y. Liu, J.-P. Wan, Org. Lett., 2021, 23,
4250-4255.
Nickel-Catalyzed Electrochemical Phosphorylation of Aryl Bromides
Y. Bai, N. Liu, S. Wang, S. Wang, S. Ning, L. Shi, L. Cui, Z. Zhang, J. Xiang,
Org. Lett., 2019, 21, 6795-6799.
Formic Acid as Carbon Monoxide Source in the Palladium-Catalyzed
N-Heterocyclization of o-Nitrostyrenes to Indoles
M. A. Fouad, F. Ferretti, F. Ragaini, J. Org. Chem., 2023, 88,
5108-5117.
Asymmetric Synthesis of Protected Unnatural α-Amino Acids via
Enantioconvergent Nickel-Catalyzed Cross-Coupling
Z.-P. Yang, D. J. Freas, G. C. Fu, J. Am. Chem. Soc.,
2021, 143, 8614-8618.
Access to Imidazolidines via 1,3-Dipolar Cycloadditions of 1,3,5-Triazinanes
with Aziridines
L. Tu, Z. Li, T. Feng, S. Yu, R. Huang, J. Li, W. Wang, Y. Zheng, J. Liu, J. Org. Chem., 2019,
84, 11161-11169.
Dual Ruthenium-Catalyzed Alkene Isomerization-Hydrogen Auto-Transfer Unlocks
Skipped Dienes as Pronucleophiles for Enantioselective Alcohol C-H Allylation
Z. J. Dubey, W. Shen, J. A. Little, M. K. Krische, J. Am. Chem. Soc.,
2023, 145, 8576-8582.
Divergent Synthesis of Substituted Amino-1,2,4-triazole Derivatives
F. Zhao, T. Singh, Y. Xiao, W. Su, D. Yang, C. Jia, J.-Q. Li, Z. Qin, Synthesis, 2021, 53,
1901-1910.
Light-Mediated Dual Phosphine-/Copper-Catalyzed Atom Transfer Radical
Addition Reaction
O. V. Fedorov, S. I. Scherbinina, V. V. Levin, A. D. Dilman, J. Org. Chem., 2019,
84, 11068-11079.
Gold-Catalyzed Anti-Markovnikov Oxidation of Au-Allenylidene to Generate
Alkylidene Ketene
X. Sun, X. Duan, N. Zheng, W. Song, Org. Lett., 2023, 25,
2798-2805.
Accessing Aliphatic Amines in C-C Cross-Couplings by Visible Light/Nickel
Dual Catalysis
W. Dong, S. O. Badir, X. Zhang, G. A. Molander, Org. Lett., 2021, 23,
4250-4255.
Organoselenium-Catalyzed Aza-Wacker Reactions: Efficient Access to
Isoquinolinium Imides and an Isoquinoline N-Oxide
H. Li, L. Liao, X. Zhao, Synlett, 2019,
30,
1688-1692.
A Convenient, Efficient, and Inexpensive Copper(I) Complex Catalyzed
Sonogashira Cross-Coupling of o-Iodoanilines with Terminal Alkynes
X. Chen, X.-Y. Zhou, Synthesis, 2023,
55, 1213-1220.
Overcoming the Naphthyl Requirement in Stereospecific Cross-Couplings to
Form Quaternary Stereocenters
J. Xu, O. P. Bercher, M. P. Watson, J. Am. Chem. Soc.,
2021, 143, 8608-8613.
Reductive Amination of Ketonic Compounds Catalyzed by Cp*Ir(III) Complexes
Bearing a Picolinamidato Ligand
K. Tanaka, T. Miki, K. Murata, A. Yamaguchi, Y. Kayaki, S. Kuwata, T. Ikariya,
M. Watanabe, J. Org. Chem., 2019,
84, 10962-10977.
Why Organic Chemists should check abstracts
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In conclusion, abstracts play an important role in helping organic chemists stay informed, find relevant research, evaluate the significance of studies, identify potential collaborators, and keep track of competitors.