Catalytic enantioselective C-C coupling - allyl transfer and Mukaiyama aldol reaction.

T. Bach, Angew. Chem., Int. Ed. Engl., 1994, 33, 417.

Key Words:



Additions to functionalized arenes with concurrent dearomatization.

T. Bach, Angew. Chem., Int. Ed. Engl., 1996, 35, 729.

Key Words:
COMPLEXES/PENTAAMMINEOSMIUM(II)



The Paterno-Buchi reaction of 3-heteroatom-substituted alkenes as a stereoselective entry to polyfunctional cyclic and acyclic molecules.

T. Bach, Liebigs Ann. Chem., 1997, 1627.

Key Words:
photochemistry/synthetic methods/oxetanes/diols/amino alcohols/SILYL ENOL ETHERS/PHOTOCHEMICAL-REACTIONS/PHOTOCYCLOADDITION REACTIONS/AROMATIC-ALDEHYDES/OXETANES/DIASTEREOSELECTIVITY/CARBOHYDROXYLATION/ISOINVERSION/SUBSTITUTION/DERIVATIVES



Stereoselective intermolecular [2+2]-photocycloaddition reactions and their application in synthesis.

T. Bach, Synthesis, 1998, 683.

Key Words:
[2+2]-photocycloaddition/Paterno-Buchi reaction/oxetanes/cyclobutanes/stereoselective synthesis/PATERNO-BUCHI REACTION/CARBONYL PHOTOCYCLOADDITION REACTION/PHOTOCHEMICAL CYCLOADDITION REACTIONS/ELECTRON-RICH OLEFINS/SILYL ENOL ETHERS/PHOTOINDUCED MOLECULAR-TRANSFORMATIONS/BENZILIC ACID REARRANGEMENT/FREE-RADICAL FRAGMENTATION/TRANS-DECALIN DERIVATIVES/CHARGE-TRANSFER PHENOMENA



The Paterno-Buchi reaction of N-acyl enamines and aldehydes - The development of a new synthetic method and its application to total synthesis and molecular recognition studies.

T. Bach, Synlett, 2000, 1699.

Key Words:
photochemistry/cycloadditions/stereoselective synthesis/ring opening/SILYL ENOL ETHERS/ASYMMETRIC PHOTOCHEMICAL-REACTIONS/RING-OPENING REACTIONS/FACIAL DIASTEREOSELECTIVITY/ANTIFUNGAL AGENT/LEWIS-ACID/STEREOSELECTIVE PHOTOCYCLOADDITION/STEREOGENIC CENTERS/1,2-AMINO ALCOHOLS/CONTROL ELEMENT