Carbenoid complexes of electron-deficient transition metals - Syntheses of and with short-lived building blocks.

R. Beckhaus, Angew. Chem., Int. Ed. Engl., 1997, 36, 687.

Key Words:
carbene complexes/cycloadditions/metallacycles/titanium/vinylidene complexes/C-H ACTIVATION/MEDIATED CARBONYL OLEFINATIONS/METALLACYCLIC ZIRCONOXYCARBENE COMPLEXES/AGOSTIC ALKENYLZIRCONOCENE COMPLEXES/TITANOCENE VINYLIDENE COMPLEXES/THERMAL-DECOMPOSITION PATHWAYS/LINEAR SEMIBRIDGING CARBONYLS/ALPHA-HYDROGEN ABSTRACTION/FISCHER-TROPSCH REACTION/SINGLE-SOURCE PRECURSOR



R. Beckhaus, in Metallocenes: Synthesis, Reactivity, Applications, Vol. 1 and 2 (Eds.: A. Togni, R. L. Halterman), Wiley-Vch, Inc, 605 Third Ave, New York, NY 10158-0012, USA, 1998, pp. 153.

Key Words:



The story of 1-alkenyl complexes of early transition metals - A low temperature access to the versatile titana-allene building block [Cp*Ti-2=C=CH2].

R. Beckhaus, J. Oster, J. Sang, I. Strauss, M. Wagner, Synlett, 1997, 241.

Key Words:
titanocene/vinylidene complexes/metathesis/metallacycles/binuclear complexes/FISCHER-CARBENE COMPLEXES/CYCLOADDITION REACTIONS/VINYLIDENE/REACTIVITY/CHEMISTRY/ZIRCONIUM/VINYLLITHIUM/DERIVATIVES/TITANOCENE/TITANACYCLOBUTANE



Carbene complexes of titanium group metals - formation and reactivity.

R. Beckhaus, C. Santamaria, J. Organomet. Chem., 2001, 617, 81.

Key Words:
carbene complexes; titanium group metals; cycoladdition reactions; TITANOCENE VINYLIDENE FRAGMENT; MEDIATED CARBONYL OLEFINATIONS; ETA(2)-N-2-TITANIUM DIAZOALKANE COMPLEX; RING-OPENING METATHESIS; R = PH; ALKYLIDENE COMPLEXES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; ZIRCONIUM COMPLEXES; HETEROBINUCLEAR COMPLEXES