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The Bonding Properties of Cyclopropane and Their Chemical Consequences.

A. de Meijere, Angew. Chem., Int. Ed. Engl., 1979, 18, 809.

Key Words:
PHYSICAL ORGANIC/REACTIVE INTERMEDIATES/STRAINED MOLECULES/CARBRING/3/CYCLOPROPANE



A. de Meijere, Vol. 4, Springer, Berlin, 1990.

Key Words:
C-C BOND FORMATION/ANNULATIONS/3-RING/Se/Si/CARBRING/3



beta-Aminosubstituted alpha,beta-unsaturated Fischer carbene complexes as chemical multitalents.

A. De Meijere, Pure Appl. Chem., 1996, 68, 61.

Key Words:
TRANSITION-METAL COMPLEXES/ORGANIC SYNTHESES/CHROMIUM/ALKYNES/TUNGSTEN



A. de Meijere, A. Kaumann, R. Lackmann, H.-C. Militzer, O. Reiser, S. Schomenauer, A. Weier, in Organometallics in Organic Synthesis. 2., Vol. 2 (Eds.: H. Werner, G. Erker), Springer, Berlin, 1989, p. 255.

Key Words:
ORGANOMETALLICS/Fe/Co/Cr



What is new in [2.2]paracyclophane chemistry?.

A. de Meijere, B. Konig, Synlett, 1997, 1221.

Key Words:
[2.2]paracyclophane/pi-systems/metal complexes/topological reaction control/DIELS-ALDER REACTIONS/RIBBON-SHAPED STRUCTURES/PHOTOCHEMICAL PROPERTIES/2+2 PHOTOCYCLOADDITION/ORGANIC-SYNTHESIS/ARENE SYNTHESIS/GENERAL-ROUTE/CYCLOPHANES/COMPLEXES/DERIVATIVES



A. De Meijere, S. Kozhushkov, in Advances in Strain in Organic Chemistry, Vol. 4 (Ed.: B. Halton), Jai Press Inc, Greenwich, CT, 1995, pp. 225.

Key Words:



A. de Meijere, S. I. Kozhushkov, in Houben-Weyl Methods of Organic Chemistry, Carbocyclic Four-Membered Ring Compounds, Vol. E17f, 4th ed. (Ed.: A. de Meijere), Georg Thieme Verlag, Stuttgart, 1997, pp. 952.

Key Words:



A. de Meijere, S. I. Kozhushkov, in Houben-Weyl Methods of Organic Chemistry, Carbocyclic Four-Membered Ring Compounds, Vol. E17f, 4th ed. (Ed.: A. de Meijere), Georg Thieme Verlag, Stuttgart, 1997, pp. 999.

Key Words:



Macrocyclic Structurally Homoconjugated Oligoacetylenes: Acetylene- and Diacetylene-Expanded Cycloalkanes and Rotanes.

A. De Meijere, S. I. Kozhushkov, Top. Curr. Chem., 1999, 201, 1.

Key Words:
Macrocycles/oligoacetylene Cycloalkanes/acetylene-expanded Rotanes/acetylene-expanded



Alkyl 2-chloro-2-cyclopropylideneacetates - Remarkably versatile building blocks for organic synthesis.

A. de Meijere, S. I. Kozhushkov, L. P. Hadjiarapoglou, Top. Curr. Chem., 2000, 207, 149.

Key Words:
absolute configuration/amines/amino acids/carbenes/cascade reactions/2-chloro-2-cyclopropylideneacetates/combinatorial libraries/cycloadditions/cyclobutenes/cyclopropanes/Diels-Alder reactions/heterocycles/Michael additions/nitrones/nucleophilic substitutions/peptidomimetics/palladium catalysis/polycycles/solid phase synthesis/spiro compounds/thiols/GLYCINE CATION EQUIVALENT/OPTICALLY-ACTIVE OXAZOLIDINONES/IMINIUM ION REARRANGEMENT/POTENT BRACKEN CARCINOGEN/AQUILINUM VAR LATIUSCULUM/CYCLOPROPANE AMINO-ACIDS/DNA CLEAVING ACTIVITIES/ACYL-COA DEHYDROGENASE/BETA-LACTAM SYNTHESIS/DIELS-ALDER REACTIONS



Bicyclopropylidene - A unique tetrasubstituted alkene and a versatile C-6-building block.

A. de Meijere, S. I. Kozhushkov, A. F. Khlebnikov, Top. Curr. Chem., 2000, 207, 89.

Key Words:
absolute configuration/amino acids/bicyclopropylidene/coupling reactions/cycloadditions/cyclopropanation/cyclopropanes/organolithium derivatives/palladium catalysis/radical reactions/small ring polycycles/spiro compounds/strain energy/sulfides/CYCLOPROPYL BUILDING-BLOCKS/SMALL-RING COMPOUNDS/ANTIFUNGAL AGENT FR-900848/VINYLCYCLOPROPYLIDENE CYCLOPENTENYLIDENE REARRANGEMENT/DIELS-ALDER REACTIONS/ORGANIC-SYNTHESIS/METHYLENECYCLOPROPANE MOIETIES/THERMAL REARRANGEMENT/BRANCHED TRIANGULANES/COUPLING REACTIONS



Fine Feathers Make Fine Birds - The Heck Reaction In Modern Garb.

A. De Meijere, F. E. Meyer, Angew. Chem., Int. Ed. Engl., 1994, 33, 2379.

Key Words:



Fine feathers make fine birds: The Heck reaction in modern garb.

A. De Meijere, F. E. Meyer, Angew. Chem., Int. Ed. Engl., 1995, 33, 2379.

Key Words:
PALLADIUM-CATALYZED SYNTHESIS/ANION CAPTURE PROCESSES/CROSS-COUPLING REACTIONS/METAL-PROMOTED CYCLIZATION/PI-ALLYLPALLADIUM COMPLEXES/PHASE-TRANSFER CONDITIONS/PLATELET-ACTIVATING FACTOR/QUATERNARY CARBON CENTERS/SUBSTITUTED ARYL HALIDES/DIELS-ALDER REACTION/Pd



Tailoring the Reactivity of Small Ring Building Blocks for Organic Synthesis.

A. de Meijere, L. Wessjohann, Synlett, 1990, 20.

Key Words:
PHYSICAL ORGANIC/REACTIVE INTERMEDIATES/STRAINED MOLECULES/CARBRING/3,4/CYCLOPROPANES/CYCLOBUTANES



A. de Meijere, F. Wolf, in Organic Peroxy Compounds, Vol. E13, 4th ed. (Ed.: H. Kropf), Georg Thieme Verlag, Stuttgart, 1988, pp. 971.

Key Words:

 

 

Palladium in action: domino coupling and allylic substitution reactions for the efficient construction of complex organic molecules.

A. deMeijere, S. Brase, J. Organomet. Chem., 1999, 576, 88.

Key Words:
Heck reaction/cross-coupling reactions/domino reaction/multi-component reaction/biologically active compounds/CYCLOPROPYL BUILDING-BLOCKS/ANION CAPTURE PROCESSES/CATALYZED TANDEM CYCLIZATION/DIELS-ALDER REACTIONS/C-H ACTIVATION/INTRAMOLECULAR HECK REACTIONS/HIGH-PRESSURE CONDITIONS/ARYL HALIDES/ASYMMETRIC-SYNTHESIS/METAL-COMPLEXES



News about acepentalene, cyclopentadienyl cations and other elusive aromatic and antiaromatic compounds.

A. deMeijere, R. Haag, F. M. Schungel, S. I. Kozhushkov, I. Emme, Pure Appl. Chem., 1999, 71, 253.

Key Words:
TRIQUINACENE/DERIVATIVES/COMPLEXES/DIHYDROACEPENTALENE/HOMOAROMATICITY/HYDROCARBONS/LIGANDS/METAL/IONS



The chemistry of highly strained oligospirocyclopropane systems.

A. deMeijere, S. I. Kozhushkov, Chem. Rev., 2000, 100, 93.

Key Words:
CYCLOPROPYL BUILDING-BLOCKS/GLYCINE CATION EQUIVALENT/SMALL-RING COMPOUNDS/SEQUENTIAL PERIPHERAL CYCLOPROPANATION/PHOTOINDUCED SKELETAL REARRANGEMENT/CYCLO-SUBSTITUTED TRIANGULANES/2-CARBON BRIDGED SPIROPENTANE/ALKYLIDENE TRANSFER REAGENTS/POTENT BRACKEN CARCINOGEN/METAL-CATALYZED-REACTIONS



An evolving multifunctional molecular building block: Bicyclopropylidene.

A. deMeijere, S. I. Kozhushkov, Eur. J. Org. Chem., 2000, 3809.

Key Words:
bicyclopropylidene/cross-coupling/cycloadditions/organometallic compounds/spiro compounds/SMALL-RING COMPOUNDS/ACYL-COA DEHYDROGENASE/ORGANIC-SYNTHESIS/METHYLENECYCLOPROPANE MOIETIES/CARBENE DIMERIZATION/TETRASUBSTITUTED ALKENES/THERMAL REARRANGEMENT/COUPLING REACTIONS/3-MEMBERED RINGS/CYCLO-ADDITIONS



Bicyclopropylidene. A unique tetrasubstituted alkene and versatile C-6-building block for organic synthesis.

A. deMeijere, S. I. Kozhushkov, T. Spath, M. vonSeebach, S. Lohr, H. Nuske, T. Pohlmann, M. EsSayed, S. Brase, Pure Appl. Chem., 2000, 72, 1745.

Key Words:
CYCLOPROPYL BUILDING-BLOCKS/SMALL RING COMPOUNDS/CARBENE DIMERIZATION/THERMAL REARRANGEMENT/COUPLING REACTIONS/AZA-ANALOGS/DERIVATIVES/1-HALOGENO-1-LITHIOCYCLOPROPANES/3-SPIROCYCLOPROPANE-4-PYRIDONE/BI(CYCLOPROPYLIDENES)



Fischer carbene complexes as chemical multitalents: The incredible range of products from carbenepentacarbonylmetal alpha,beta-unsaturated complexes.

A. deMeijere, H. Schirmer, M. Duetsch, Angew. Chem., Int. Ed. Engl., 2000, 39, 3964.

Key Words:
alkynes/carbene complexes/cycloadditions/domino reactions/insertion/TRANSITION-METAL COMPLEXES/CYCLOPROPYLCARBENE-CHROMIUM COMPLEXES/DIELS-ALDER REACTIONS/TUNGSTEN PENTACARBONYL GROUPS/X-RAY STRUCTURE/M = CR/DIASTEREOSELECTIVE 3+2 CYCLOADDITION/ALKENE AMINOCARBENE COMPLEXES/STATE ADSORPTION CONDITIONS/ELECTRON-DEFICIENT OLEFINS