Catalytic Methods for Metal Carbene Transformations.

M. P. Doyle, Chem. Rev., 1986, 86, 919.

Key Words:
PHYSICAL ORGANIC/REACTIVE INTERMEDIATES/CARBENOIDS/RHODIUM ACETATE/CARBENE FORMATION/CYCLOPROPANES/Rh



Chiral catalysts for enantioselective carbenoid cyclopropanation reactions.

M. P. Doyle, Recl. Trav. Chim. Pays-Bas, 1991, 110, 305.

Key Words:



M. P. Doyle, in Catalytic Asymmetric Synthesis (Ed.: I. Ojima), VCH, New York, 1993, pp. 63.

Key Words:
RHODIUM/Rh/COPPER/Cu



Asymmetric syntheses with catalytic enantioselective metal carbene transformations.

M. P. Doyle, Russian Chemical Bulletin, 1994, 43, 1770.

Key Words:
ASYMMETRIC CATALYSIS, METAL CARBENE TRANSFORMATIONS/DIRHODIUM(II) CARBOXAMIDES/ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION/ENANTIOSELECTIVE INERTMOLECULAR CYCLOPROPENATION/ENANTIOSELECTIVE INTRAMOLECULAR CARBON-HYDROGEN INSERTION/DIAZOACETATES AND DIAZOACETAMIDES/DIASTEREOSELECTION/REGIOSELECTION/LACTONE SYNTHESIS/LACTAM SYNTHESIS/CHIRAL RHODIUM(II) CARBOXAMIDES/HYDROGEN INSERTION REACTIONS/RESTRICTED PEPTIDE ISOSTERES/DIAZO-CARBONYL-COMPOUNDS/CYCLOPROPANATION REACTIONS/INTRAMOLECULAR CYCLOPROPANATIONS/DIRHODIUM(II) CARBOXYLATES/ORGANIC-SYNTHESIS/LIGANDS/OLEFINS/Rh



M. P. Doyle, in Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994, Vol. 12 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, UK, 1995, pp. 387.

Key Words:
TM



M. P. Doyle, in Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994, Vol. 12 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, UK, 1995, pp. 421.

Key Words:
TM



M. P. Doyle, JAI, Greenwich, CT, 1995.

Key Words:



Chiral Dirhodium Carboxamidates Catalysts for Highly Enantioselective Syntheses of Lactones and Lactams.

M. P. Doyle, Aldrichimica Acta, 1996, 29, 3.

Key Words:



New catalysts and methods for highly enantioselective metal carbene reactions.

M. P. Doyle, Pure Appl. Chem., 1998, 70, 1123.

Key Words:
HYDROGEN INSERTION REACTIONS/CHIRAL LIGANDS/DIAZOCARBONYL COMPOUNDS/ASYMMETRIC-SYNTHESIS/ALKYL DIAZOACETATES/ORGANIC-SYNTHESIS/CYCLOPROPANATION/TRANSFORMATIONS/DIASTEREOCONTROL/ENANTIOCONTROL



M. P. Doyle, in Catalysis by di- and Polynuclear Metal Cluster Complexes (Eds.: R. D. Adams, F. A. Cotton), Wiley-VCH, Inc, 605 Third Ave/New York/NY 10158-0012, 1998, pp. 249.

Key Words:



Enantiocontrol in catalytic metal carbene reactions.

M. P. Doyle, Russian Chemical Bulletin, 1999, 48, 16.

Key Words:
enantiocontrol/enantioselective reactions/metal carbenes/catalysis/CARBON-HYDROGEN INSERTION/RESTRICTED PEPTIDE ISOSTERES/SI-H BOND/INTRAMOLECULAR CYCLOPROPANATION/HIGH ENANTIOSELECTIVITY/ALKYL DIAZOACETATES/CHIRAL CATALYSTS/TRANSFORMATIONS/LACTONES/DIASTEREOCONTROL



Recent advances in asymmetric catalytic metal carbene transformations.

M. P. Doyle, D. C. Forbes, Chem. Rev., 1998, 98, 911.

Key Words:
CARBON-HYDROGEN INSERTION/C-H INSERTION/ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION/BETA-KETO-ESTERS/HOMOCHIRAL RHODIUM(II) CARBOXYLATES/BIS-OXAZOLINE LIGANDS/OPTICALLY-ACTIVE SILOXYCYCLOPROPANES/SECONDARY ALLYLIC DIAZOACETATES/TRANS-WHISKEY LACTONE/CHIRAL CATALYSTS



Macrocycle formation from catalytic metal carbene transformations.

M. P. Doyle, W. H. Hu, Synlett, 2001, 1364.

Key Words:
macrocylization; dirhodium(II) catalysts; copper(I) catalysts; asymmetric induction; addition reactions; coupling; INTRAMOLECULAR CYCLOPROPANATION; ENANTIOCONTROL; MACROLIDES; INSERTION; LACTONES; OXONIUM



Recent advances in stereoselective synthesis involving diazocarbonyl intermediates.

M. P. Doyle, M. A. McKervey, J. Chem. Soc., Chem. Commun., 1997, 983.

Key Words:
HOMOCHIRAL RHODIUM(II) CARBOXYLATES/HYDROGEN INSERTION REACTIONS/METAL CARBENE TRANSFORMATIONS/RESTRICTED PEPTIDE ISOSTERES/C-H INSERTION/L-AMINO-ACIDS/ALPHA-DIAZOKETONES/ASYMMETRIC-SYNTHESIS/ORGANIC-SYNTHESIS/CHIRAL LIGANDS



M. P. Doyle, M. A. McKervey, T. Ye, Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: From Cyclopropanes to Ylides., Wiley, New York, 1998.

Key Words:



New aspects of catalytic asymmetric cyclopropanation.

M. P. Doyle, M. N. Protopopova, Tetrahedron, 1998, 54, 7919.

Key Words:
ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION/METAL CARBENE TRANSFORMATIONS/HOMOCHIRAL RHODIUM(II) CARBOXYLATES/CHIRAL DIRHODIUM(II) CARBOXAMIDES/SECONDARY ALLYLIC DIAZOACETATES/RESTRICTED PEPTIDE ISOSTERES/OPTICALLY-ACTIVE BIPYRIDINE/CARBON-HYDROGEN INSERTION/BIS-OXAZOLINE LIGANDS/DIAZO-COMPOUNDS



M. P. Doyle, T. Ren, in Prog. Inorg. Chem., Vol. 49 (Ed.: K. D. Karlin), John Wiley & Sons Inc, 2001, pp. 113.

Key Words: