Prototropic Routes to 1,3- and 1,5-Dipoles, and 1,2-Ylides: Applications to the Synthesis of Heterocyclic Compounds.

R. Grigg, Chem. Soc. Rev., 1987, 16, 89.

Key Words:
C-C BOND FORMATION/HETEROANNULATIONS/PERICYCLIC REACTIONS/CYCLOADDITIONS/[3+2]/1,3-DIPOLES/1,5-DIPOLES/1,2-YLIDES/HETRING/5(N)/HETRING/5(N,O)/HETEROCYCLES



R. Grigg, V. Sridharan, in Advances in Cycloaddition, Vol. 3 (Ed.: D. P. Curran), Jai Press Inc, Greenwich, CT, 1993, pp. 161.

Key Words:



R. Grigg, V. Sridharan, in Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994, Vol. 12 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, UK, 1995, pp. 299.

Key Words:
TM



Heterocycles via Pd catalysed molecular queuing processes. Relay switches and the maximisation of molecular complexity.

R. Grigg, V. Sridharan, Pure Appl. Chem., 1998, 70, 1047.

Key Words:
ANION CAPTURE PROCESSES/INTRAMOLECULAR HECK REACTIONS/METAL-PROMOTED CYCLIZATION/QUATERNARY CARBON CENTERS/TANDEM CYCLIZATION/CYCLIC CARBOPALLADATION/SILVER-NITRATE/PALLADIUM/ARYLATION/CONSTRUCTION



Palladium catalysed cascade cyclisation-anion capture, relay switches and molecular queues.

R. Grigg, V. Sridharan, J. Organomet. Chem., 1999, 576, 65.

Key Words:
palladium/catalysis/cyclic carbopalladation/anion-capture/carbonylation/allenes/heterocyclic synthesis/polycyclisation/INTRAMOLECULAR HECK REACTIONS/STEPWISE SUCCESSIVE INSERTION/FUNCTIONALLY-SUBSTITUTED ARYL/METAL-PROMOTED CYCLIZATION/QUATERNARY CARBON CENTERS/TANDEM CYCLIZATION/QUEUING CASCADES/CARBONYLATIVE CYCLIZATION/CYCLIC CARBOPALLADATION/SYNTHETIC METHODOLOGY