Carboranylhalonium ions: from striking reactivity to a unified mechanistic analysis of polar reactions of diarylhalonium compounds.

V. V. Grushin, Acc. Chem. Res., 1992, 25, 529.

Key Words:
B/BORON



Reductive elimination of hydrogen chloride from chloro hydrido transition metal complexes: an efficient and simple method for generation of electron-rich, coordinatively unsaturated, reactive intermediates.

V. V. Grushin, Acc. Chem. Res., 1993, 26, 279.

Key Words:
TM



Hydride complexes of palladium.

V. V. Grushin, Chem. Rev., 1996, 96, 2011.

Key Words:
TRANSITION-METAL-COMPLEXES/X-RAY CRYSTAL/PD-H BOND/UNUSUAL COORDINATION BEHAVIOR/OXIDATIVE ADDITION-REACTION/TERTIARY PHOSPHINE-LIGANDS/MANDELIC-ACID DERIVATIVES/POTENTIAL-ENERGY SURFACES/ELECTRON-SPIN-RESONANCE/C-C BONDS



Cyclic diaryliodonium ions: old mysteries solved and new applications envisaged.

V. V. Grushin, Chem. Soc. Rev., 2000, 29, 315.

Key Words:
NUCLEOPHILIC-SUBSTITUTION/SALTS/CATIONS/ATOM



Palladium fluoride complexes: One more step toward metal-mediated C-F bond formation

V. V. Grushin, Chem. Eur. J., 2002, 8, 1006.

Key Words:
fluorination/naked fluoride/palladium/transition metals/SELECTIVE FLUORINATION/DIARYLIODONIUM SALTS/ACETYL HYPOFLUORITE/AROMATIC-COMPOUNDS/CARBON-HETEROATOM/ORGANIC-SYNTHESIS/ARYL/ION/LIGANDS/CATALYSIS



Transformations of Chloroarenes, Catalyzed by Transition-Metal Complexes.

V. V. Grushin, H. Alper, Chem. Rev., 1994, 94, 1047.

Key Words:
TM