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Palladium-catalyzed amination of aryl halides: Mechanism and rational catalyst design.

J. F. Hartwig, Synlett, 1997, 329.

Key Words:
amination/amido complex/palladium/coupling/reductive elimination/CROSS-COUPLING REACTIONS/OXYGEN-ATOM TRANSFER/N-H ACTIVATION/REDUCTIVE ELIMINATION/TRANSITION-METAL/OXIDATIVE ADDITION/NITROUS-OXIDE/NUCLEOPHILIC-SUBSTITUTION/ORGANIC ELECTROPHILES/ORGANOTIN REAGENTS



Transition metal catalyzed synthesis of arylamines and aryl ethers from aryl halides and triflates: Scope and mechanism.

J. F. Hartwig, Angew. Chem., Int. Ed. Engl., 1998, 37, 2047.

Key Words:
aminations/arylations/ethers/nickel/palladium/FORMING REDUCTIVE ELIMINATION/CROSS-COUPLING REACTIONS/NITROGEN BOND FORMATION/TRIS(O-TOLYL)PHOSPHINE MONO(AMINE) COMPLEXES/BETA-HYDROGEN ELIMINATION/ARENE-RUTHENIUM CHEMISTRY/SOLID-PHASE SYNTHESIS/OXYGEN-ATOM TRANSFER/OXIDATIVE ADDITION/ORGANOBORON COMPOUNDS



Carbon-heteroatom bond-forming reductive eliminations of amines, ethers, and sulfides.

J. F. Hartwig, Acc. Chem. Res., 1998, 31, 852.

Key Words:
PALLADIUM-CATALYZED SYNTHESIS/CROSS-COUPLING REACTION/OXYGEN-ATOM TRANSFER/ARYL HALIDES/DIARYL SULFIDES/NITROUS-OXIDE/NICKEL ALKYLS/COMPLEXES/AMINATION/BROMIDES



Approaches to catalyst discovery. New carbon-heteroatom and carbon-carbon bond formation.

J. F. Hartwig, Pure Appl. Chem., 1999, 71, 1417.

Key Words:
FORMING REDUCTIVE ELIMINATION/BETA-HYDROGEN ELIMINATION/CROSS-COUPLING REACTIONS/ARYL HALIDE AMINATION/ALPHA-ARYLATION/PALLADIUM/COMPLEXES/BROMIDES/ARYLAMINES/NITROGEN



Modern Methods for the Radical Deoxygenation of Alcohols.

W. Hartwig, Tetrahedron, 1983, 39, 2609.

Key Words:
FUNCTIONAL GROUPS/REDUCTION/METAL HYDRIDE/C-X/OH/ALKOHOLS/TIN HYDRIDE/R3SnH/RADICAL DEOXYGENATION/REDUCTION/ALKANES/Sn