Dialkyl 1-alkynylphosphonates: A range of promising reagents.

B. Iorga, F. Eymery, D. Carmichael, P. Savignac, Eur. J. Org. Chem., 2000, 3103.

Key Words:
1-alkynylphosphonates/cycloadditions/eliminations/dehalogenation/hydration/reductions/SNP(V)/CONVENIENT STEREOSELECTIVE SYNTHESIS/NUCLEOPHILIC-SUBSTITUTION/PHOSPHINE OXIDE/PHOSPHONATES/ACETYLENES/ACID/ALKYNYLPHOSPHONATES/CYCLOADDITION/REACTIVITY/ENAMINES



Phosphorylated aldehydes: Preparations and synthetic uses.

B. Iorga, F. Eymery, V. Mouries, P. Savignac, Tetrahedron, 1998, 54, 14637.

Key Words:
ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS/WADSWORTH-EMMONS REAGENTS/SOLID-PHASE SYNTHESIS/DIELS-ALDER REACTIONS/METHYL CERIFERATE-I/PHOSPHONATE ANALOGS/ORGANIC-SYNTHESIS/ENANTIOSELECTIVE SYNTHESIS/GENERAL-SYNTHESIS/ALDOL REACTIONS



The syntheses and properties of 1,2-epoxyalkylphosphonates.

B. Iorga, F. Eymery, P. Savignac, Synthesis, 1999, 207.

Key Words:
Darzens reaction/halohydrins/halo ketones/fosfomycin/opening and rearrangement reactions/P-C BOND/ALPHA-HETEROSUBSTITUTED EPOXIDES/OXIRANE OXYGEN ATOM/STREPTOMYCES-FRADIAE/NATURAL-PRODUCTS/CARBONYL-COMPOUNDS/FOSFOMYCIN PHOSPHONOMYCIN/ASYMMETRIC-SYNTHESIS/SILYL PHOSPHITES/ACID FOSFOMYCIN



Controlled reactivity of phosphonates by temporary silicon connection.

B. Iorga, P. Savignac, Synlett, 2001, 447.

Key Words:
phosphonate carbanion; Peterson reaction; silicon; halogenation; alkylation; HORNER-EMMONS REACTION; ALPHA-FLUOROALKYLPHOSPHONATES; FLUORIDE-ION; CONTROLLED MONOHALOGENATION; OLEFINATION REACTION; EFFICIENT SYNTHESIS; CARBONYL-COMPOUNDS; ROUTE; VINYLPHOSPHONATES; ACID