Synthesis of higher carbon sugars by a ''tail-to-tail'' coupling of simple monosaccharides.

S. Jarosz, Pol. J. Chem., 1996, 70, 141.

Key Words:
ALLYLIC ALCOHOLS/C-DISACCHARIDES/HIGH-PRESSURE/STEREOSELECTIVE SYNTHESIS/NUCLEOPHILIC OPENINGS/2,3-EPOXY ALCOHOLS/CHAIN ELONGATION/CHEMISTRY/1-METHOXYBUTA-1,3-DIENE/STEREOCHEMISTRY



The chemistry of sucrose.

S. Jarosz, Pol. J. Chem., 1996, 70, 972.

Key Words:
CARBOHYDRATES/SUCROSE/SUCROSE DERIVATIVES SYNTHESIS/STREPTOCOCCUS-D-GLUCANSUCRASES/OCTA-O-ACETYLSUCROSE/STEREOSELECTIVE SYNTHESIS/CHEMOENZYMATIC SYNTHESIS/REGIOSELECTIVE SYNTHESIS/TRITYLATED SUCROSE/DERIVATIVES/SUCROCHEMISTRY/INHIBITION/COPOLYMERIZATION



Synthesis and application of allyltin derivatives in organic chemistry.

S. Jarosz, E. Kozlowska, Pol. J. Chem., 1998, 72, 815.

Key Words:
allyltin derivatives/radical reactions/stannyl anions/CARBON BOND FORMATION/ORGANOTIN COMPOUNDS/SUBSTITUTED ALLYLSTANNANES/THERMAL-REACTIONS/ALDEHYDES/REAGENTS/STANNANES/ALCOHOLS/ROUTE/TIN



Regio- and stereoselective transformations of sucrose at the terminal positions

S. Jarosz, M. Mach, Eur. J. Org. Chem., 2002, 769.

Key Words:
carbohydrates/crown compounds/dihydroxylation/protecting groups/Wittig reaction/synthesis design/DOUBLE ASYMMETRIC INDUCTION/OCTURONIC ACID-DERIVATIVES/OCTA-O-ACETYLSUCROSE/HIGHER-CARBON SUGARS/REGIOSELECTIVE SYNTHESIS/CATALYTIC OSMYLATION/UNPROTECTED SUCROSE/TRITYLATED SUCROSE/OLEFIN METATHESIS/HYDROXYL-GROUPS