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Synthetic Methods Using alpha-Heterosubstituted Organometallics.

A. Krief, Tetrahedron, 1980, 36, 2531.

Key Words:
ORGANOMETALLICS/SYNTHESIS/C-M(X)



Synthesis and Synthetic Applications of 1-Metallo-1-seleno-cyclopropanes and -cyclobutanes and Related 1-Metallo-1-silyl-cyclopropanes.

A. Krief, Top. Curr. Chem., 1986, 135, 1.

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A. Krief, in The Chemistry of Organic Selenium and Tellurium Compounds, Vol. 2 (Ed.: S. Patai), Wiley, New York, 1987, pp. 675.

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A. Krief, in Comprehensive Organic Synthesis, Vol. 3 (Eds.: B. M. Trost, I. Fleming), Pergamon Press, Oxford, 1991, p. 85.

Key Words:
C-C BOND FORMATION/APPENDAGES/ALKYLATION/S/Se



A. Krief, in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon Press, Oxford, 1991, p. 629.

Key Words:
SELENIUM/Se



A. Krief, in Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994, Vol. 11 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, UK, 1995, pp. 515.

Key Words:
Se



Asymmetric dihydroxylation of C,C double bonds using catalytic amounts of osmium tetroxide, selenides, and air

A. Krief, C. ColauxCastillo, Pure Appl. Chem., 2002, 74, 107.

Key Words:
OLEFINS/OXIDATION/LIGAND



Reactions involving inorganic compounds.

A. Krief, C. Delmotte, C. ColauxCastillo, Pure Appl. Chem., 2000, 72, 1709.

Key Words:
CATALYTIC ASYMMETRIC DIHYDROXYLATION



Original Syntheses of Epoxides Involving Organoselenium Intermediates.

A. Krief, W. Dumont, D. Van Ende, S. Halazy, D. Labar, J.-L. Laboureur, T. Q. Le, Heterocycles, 1989, 28, 1203.

Key Words:
C-C BOND FORMATION/HETEROANNULATIONS/3-RING/SELENIUM/C-M(X)/Li(Se)/X-C-C-Y/O,Se/HETRING/3(O)/EPOXIDES/OXIRANES/Se



A. Krief, L. Hevesi, Organoselenium Chemistry I. Functional Group Transformations., Springer, Berlin, 1988.

Key Words:
ORGANOMETALLICS/SELENIUM/SeO2/OXIDATION/EPOXIDATION/Se



Transformations of -hydroxyalkyl selenides to aldehydes and ketones: a review.

A. Krief, J. L. Laboureur, W. Dumont, D. Labar, Bull. Soc. Chim. Fr., 1990, 681.

Key Words:
Se



A. Krief, J. L. Laboureur, M. Hobe, P. Barbeaux, in Studies in Natural Products Chemistry, Vol.8: Stereoselective Synthesis, Part E (Ed.: Atta-ur-Rahman), Elsevier, Amsterdam, Netherlands, 1991, pp. 3.

Key Words:



o-Nitrophenyl selenocyanate, a valuable reagent in organic synthesis: Application to one of the most powerful routes to terminal olefins from prim-alcohols (the Grieco-Sharpless olefination reaction) and to the regioselective isomerisation of allyl alcohols.

A. Krief, A. M. Laval, Bull. Soc. Chim. Fr., 1997, 134, 869.

Key Words:
alcohol/alkyl selenide/olefin synthesis/oxidation/selenoxide/allyl selenide/[2,3] sigmatropic rearrangement/allyl alcohol synthesis/ASYMMETRIC TOTAL SYNTHESIS/ORGANOSELENIUM CHEMISTRY/ENANTIOSELECTIVE SYNTHESIS/ELIMINATION/CONFIGURATION/SELENOXIDES/CONVERSION/SELENIDES/KETONES/SYNTHON



Coupling of organic halides with carbonyl compounds promoted by SmI2, the Kagan reagent.

A. Krief, A. M. Laval, Chem. Rev., 1999, 99, 745.

Key Words:
DIVALENT LANTHANIDE DERIVATIVES/NUCLEOPHILIC ACYL SUBSTITUTION/BOND-FORMING REACTIONS/HEXAMETHYLPHOSPHORIC TRIAMIDE HMPA/CONJUGATE ADDITION-REACTIONS/REFORMATSKY-TYPE REACTIONS/BARBIER-TYPE REACTION/SAMARIUM(II) IODIDE/SEQUENCED REACTIONS/REDUCTIVE CYCLIZATION