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Enantioselective carbometallation of unactivated olefins.

I. Marek, J. Chem. Soc., Perkin Trans. 1, 1999, 535.

Key Words:
CATALYZED KINETIC RESOLUTION/CYCLOPROPYL ZINC REAGENTS/ASYMMETRIC-SYNTHESIS/MONOSUBSTITUTED ALKENES/ORGANOLITHIUM ADDITIONS/ANIONIC CYCLIZATIONS/STYRENE DERIVATIVES/NORMAL-BUTYLLITHIUM/ARYL CYCLOPROPANES/ALLYLIC ALCOHOLS



Synthesis and reactivity of sp(2) geminated organobismetallic derivatives.

I. Marek, Chem. Rev., 2000, 100, 2887.

Key Words:
STABILIZED ALKENYL CARBANIONS/POLYLITHIUM ORGANIC-COMPOUNDS/C-H INSERTION/GRIGNARD-REAGENTS/CARBON-CARBON/DIASTEREOSELECTIVE CARBOMETALATION/SUBSTITUTED VINYLSTANNANES/INTRAMOLECULAR CYCLIZATION/STEREOSELECTIVE SYNTHESIS/ORGANOMAGNESIUM COMPOUNDS



Synthesis and reactivity of sp(3)-geminated organodimetallics.

I. Marek, J. F. Normant, Chem. Rev., 1996, 96, 3241.

Key Words:
HINDERED ORGANOBORON GROUPS/BORON-WITTIG REACTION/DIMESITYLBORON STABILIZED CARBANIONS/DIMETALLIC ORGANIC-COMPOUNDS/GEM-BORAZIRCONOCENE ALKANES/CYCLOPROPYL ZINC REAGENTS/ALLYLIC ORGANOBISMETALLIC REAGENTS/METALLA-CLAISEN REARRANGEMENT/LITHIUM-TITANIUM EXCHANGE/CROSS-COUPLING REACTION



I. Marek, J. F. Normant, in Metal-Catalyzed Cross-Coupling Reactions (Eds.: F. Diederich, P. J. Stang), Wiley-VCH, Inc, 605 Third Ave/New York/NY 10158-0012, 1998, pp. 271.

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