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Bimetallic Catalytic Systems Containing Titanium, Zirconium, Nickel, And Palladium. Their Application to Selective Organic Synthesis.

E. Negishi, Pure Appl. Chem., 1981, 53, 2333.

Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/ALKENES/ORGANOMETALLICS/TITANIUM/ZIRCONIUM/NICKEL/PALLADIUM/C-M/Ti/Zr/Ni/Pd/CARBOMETALLATION/Al/COUPLING/C=C-C=C/E,Z/C=C-C=C/E,E/C=C-M/Al/C=C-C-C-X/OH/C=C-X/Br/I/C=C-C-X/OH



E. Negishi, in Comprehensive Organometallic Chemistry, Vol. 7 (Eds.: G. Wilkinson, F. G. A. Stone, E. Abel), Pergamon, Oxford, 1982, pp. 255.

Key Words:
ORGANOMETALLICS/BORON/C=C-M/B/Ar-M/B/C-M/B



Controlled Carbometallation as a Tool for Carbon-Carbon Bond Formation and its Application to Cyclisation.

E. Negishi, Acc. Chem. Res., 1987, 20, 65.

Key Words:
ORGANOMETALLICS/ZIRCONIUM/C-X/Zr/ANNULATION CARBOMETALLATION



E. Negishi, in Advances in Metal-Organic Chemistry, Vol. 1 (Ed.: L. S. Liebeskind), Jai Press, Inc., Greenwich, CT, 1989.

Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/ALKENES/ORGANOMETALLICS/ELEMENT/NICKEL/PALLADIUM/Ni/Pd



Cyclization, coupling, and rearrangement reactions of organozirconium and related compoumds.

E. Negishi, Chem. Scr., 1989, 29, 457.

Key Words:
ORGANOMETALLICS/ZIRCONIUM/Zr



E. Negishi, in Comprehensive Organic Synthesis, Vol. 5 (Eds.: B. M. Trost, I. Fleming), Pergamon Press, Oxford, 1991, p. 1163.

Key Words:
ORGANOMETALLICS/ZIRCONIUM/C-C BOND FORMATION/ANNULATION/5-RING/Zr



Zipper-mode cascade carbometalation for construction of polycyclic structures.

E. Negishi, Pure Appl. Chem., 1992, 64, 323.

Key Words:



Recent advances in the chemistry of zirconocene and related compounds.

E. Negishi, Ed., Tetrahedron Symposium-in-Print, 1995, 51, 4255.

Key Words:
Zr/ZIRCONIUM



Novel and selective alpha-substitution of ketones and other carbonyl compounds based on Pd-catalyzed cross coupling of alpha,beta-unsaturated carbonyl derivatives containing alpha-halogen or alpha-metal groups.

E. Negishi, J. Organomet. Chem., 1999, 576, 179.

Key Words:
alpha-substitution of carbonyl compounds/Pd-catalyzed cross coupling/alpha-halo-alpha,beta-unsaturated carbonyl compounds/alpha-metallo-alpha,beta-unsaturated carbonyl compounds/BETA-DICARBONYL COMPOUNDS/SILYL ENOL ETHERS/REFORMATSKY REAGENT/BOND FORMATION/ALK-1-ENYL-LEAD TRIACETATES/CEPHALOSPORIN CHEMISTRY/ZEROVALENT COMPLEXES/PALLADIUM CATALYSIS/ORGANOTIN COMPOUNDS/ALKENYL HALIDES



Principle of activation of electrophiles by electrophiles through dimeric association - Two are better than one.

E. Negishi, Chem. Eur. J., 1999, 5, 411.

Key Words:
aluminum/dimerization/electron deficiency/Lewis acids/zirconium/TRANSITION-METAL CATALYSIS/CARBON BOND FORMATION/BRIDGED TETRAHYDROINDENYL LIGANDS/ANSA-METALLOCENE DERIVATIVES/CP2ZR(H)CL SCHWARTZ REAGENT/CONTROLLED CARBOMETALATION/ORGANOZIRCONIUM COMPOUNDS/CASCADE CARBOALUMINATION/MONOSUBSTITUTED ALKENES/TITANOCENE DERIVATIVES



Some newer aspects of organozirconium chemistry of relevance to organic synthesis. Zr-Catalyzed enantioselective carbometallation.

E. Negishi, Pure Appl. Chem., 2001, 73, 239.

Key Words:
TRANSITION-METAL CATALYSIS; CARBON BOND FORMATION; CONTROLLED CARBOMETALATION; MONOSUBSTITUTED ALKENES; CONVENIENT PROCEDURE; ZIRCONIUM; ZIRCONOCENE; HYDROZIRCONATION; REAGENTS; ALKYNES



Thexylborane - A Highly Versatile Reagent for Organic Synthesis via Hydroboration.

E. Negishi, H. C. Brown, Synthesis, 1974, 77.

Key Words:
REAGENTS/C-M/B/THEXYLBORANE/C=C/ALKENES/C=C-C=C/DIENES/ACIDS/O=C-OH/HYDROMETALLATION/HYDROBORATION/REDUCTION/C-X/OH/ALKOHOLS/O=C-H/KETONES/ALDEHYDES



E. Negishi, D. Choueiry, in Preparation of Alkenes. A Practical Approach (Eds.: J. M. J. Williams, C. J. Moody), Oxford University Press, Oxford, U. K., 1996, pp. 137.

Key Words:



Zirconium-catalyzed enantioselective carboalumination of ''unactivated'' alkenes as a new synthetic tool for asymmetric carbon-carbon bond formation

E. Negishi, S. Q. Huo, Pure Appl. Chem., 2002, 74, 151.

Key Words:
CONTROLLED CARBOMETALATION/MONOSUBSTITUTED ALKENES/METAL CATALYSIS/ZIRCONOCENE/POLYMERIZATION/DERIVATIVES/COMPLEXES/REAGENTS/ALKYNES/METHYLALUMINATION



Formation of Carbon-Carbon and Carbon-Heteroatom Bonds via Organoboranes and Organoborates.

E. Negishi, M. J. Idacavage, Org. React. (N.Y.), 1985, 33, 1.

Key Words:
ORGANOMETALLICS/BORON/B



An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes.

E. Negishi, D. Y. Kondakov, Chem. Soc. Rev., 1996, 25, 417.

Key Words:
METAL-PROMOTED CYCLIZATION/CARBON BOND FORMATION/CONTROLLED CARBOMETALATION/CONVENIENT PROCEDURE/ORGANOZIRCONIUM COMPOUNDS/ZIRCONOCENE DERIVATIVES/MONOSUBSTITUTED ALKENES/HYDROGEN ABSTRACTION/GRIGNARD-REAGENTS/COMPLEXES



Regio- and stereoselective synthesis of gamma-alkylidenebutenolides and related compounds.

E. Negishi, M. Kotora, Tetrahedron, 1997, 53, 6707.

Key Words:
PALLADIUM-CATALYZED CARBONYLATION/METAL-PROMOTED CYCLIZATION/ENOL-LACTONES/GONIOBUTENOLIDE-A/ALKYNOIC ACIDS/UNSATURATED LACTONES/CONVENIENT SYNTHESIS/ACETYLENIC-COMPOUNDS/ALKYLIDENE LACTONES/EFFICIENT SYNTHESIS



E. Negishi, F. Liu, in Metal-Catalyzed Cross-Coupling Reactions (Eds.: F. Diederich, P. J. Stang), Wiley-VCH, Inc, 605 Third Ave/New York/NY 10158-0012, 1998, pp. 1.

Key Words:



E. Negishi, J. L. Montchamp, in Metallocenes: Synthesis, Reactivity, Applications, Vol. 1 and 2 (Eds.: A. Togni, R. L. Halterman), Wiley-Vch, Inc, 605 Third Ave, New York, NY 10158-0012, USA, 1998, pp. 241.

Key Words:



Organozirconium Compounds as New Reagents and Intermediates.

E. Negishi, T. Takahashi, Aldrichimica Acta, 1985, 18, 31.

Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/HETEROALKENES/ORGANOMETALLICS/ZIRCONIUM/C-C BOND FORMATION/ANNULATIONS/4-RING/5-RING/ALKENES/C-M/Zr/HYDROMETALLATION/Zr/CARBOMETALLATION/Zr/CARBOMETALLATION/Al/HALOGENOLYSIS/TRANSMETALLATION/CARBONYLATION/COUPLING



Organozirconium Compounds in Organic Synthesis.

E. Negishi, T. Takahashi, Synthesis, 1988, 1.

Key Words:
ORGANOMETALLICS/ZIRCONIUM/Zr



E. Negishi, T. Takahashi, in Reviews on Heteroatom Chemistry, Vol. 6 (Ed.: S. Oae), MYU K.K., Tokyo, Japan, 1992.

Key Words:
Zr



Palladium- or Nickel-Catalysed Cross Coupling. A New Selective Method for C-C Bond Formation.

E.-i. Negishi, Acc. Chem. Res., 1982, 15, 340.

Key Words:
ORGANOMETALLICS/NICKEL/PALLADIUM/COUPLING/ALKENES/ALKANES/Ni/Pd



Cyclic carbopalladation. A versatile synthetic methodology for the construction of cyclic organic compounds.

E. I. Negishi, C. Coperet, S. M. Ma, S. Y. Liou, F. Liu, Chem. Rev., 1996, 96, 365.

Key Words:
CATALYTIC ASYMMETRIC-SYNTHESIS/METAL-PROMOTED CYCLIZATION/ANION CAPTURE PROCESSES/INTRAMOLECULAR HECK REACTIONS/MEDIATED TETRAENE CARBOCYCLIZATIONS/QUATERNARY CARBON CENTERS/STEREOSPECIFIC GROUP TRANSFER/NATURAL PRODUCT SYNTHESIS/CIS-DECALIN DERIVATIVES/POLYFUSED RING-SYSTEMS



E.-i. Negishi, D. Choueiry, in Comprehensive Organic Functional Group Transformations, Vol. 2 (Eds.: A. R. Katritzky, O. Meth-Cohn, C. W. Rees), Elsevier Science, Oxford, U.K., 1995, pp. 951.

Key Words:



E.-i. Negishi, T. Takahashi, in Organometallics: Compounds of Groups 7-3 (Mn, Cr, V, Ti, Sc, La, Ac, Vol. 2 (Ed.: T. Imamoto), Georg Thieme Verlag, Stuttgart - New York, 2002, pp. 681.

Key Words:



Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest.

E.-I. Negishi, T. Takahashi, Acc. Chem. Res., 1994, 27, 124.

Key Words:
Zr