Suzuki-Miyaura Cross-Coupling of Benzylic Phosphates with Arylboronic Acids
Mark McLaughlin*
*Department of Process Research, Merck Research Laboratories, P.O. Box 2000,
Rahway, New Jersey 07065, Email: mark_mclaughlin
merck.com
M. McLaughlin, Org. Lett., 2005, 7, 4875-4878.
DOI: 10.1021/ol0517271
Abstract
Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids using a simple catalytic system of palladium(II) acetate and triphenylphosphine with either potassium phosphate or potassium carbonate as the base and toluene as the solvent at 90°C allows the preparation of a series of structurally diverse diarylmethanes.
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Key Words
ID: J54-Y2005-1760
