Highly Stereospecific, Cross-Coupling Reactions of Alkenylsilacyclobutanes

Scott E. Denmark* and Jun Young Choi

*Roger Adams Laboratory, Department of Chemistry University of Illinois, Urbana, Illinois 61801, Email: denmarkscs.uiuc.edu

S. E. Denmark, J. Am. Chem. Soc., 1999, 121, 5821-5822.

DOI: 10.1021/ja9908117 (free Supporting Information)

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Abstract

Stereospecific coupling reactions of readily available alkenylsilanes have been developed.

see article for more examples and reactions

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Stereospecific Palladium-Catalyzed Cross-Coupling of (E)- and (Z)-Alkenylsilanolates with Aryl Chlorides

S. E. Denmark, J. M. Kallemeyn, J. Am. Chem. Soc., 2006, 128, 15958-19959.

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Key Words

Hiyama Coupling, Silanes, Arenes, Dienes

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ID: J48-Y1999-390