Pd(II)-Bipyridine Catalyzed Conjugate Addition of Arylboronic Acid to α,β-Unsaturated Carbonyl Compounds
Xiyan Lu* and Shaohui Lin
*State Key Laboratory of Organometallic Chemistry, Shanghai Institute of
Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032,
China, Email: xylu
mail.sioc.ac.cn
X. Lu, S. Lin, J. Org. Chem., 2005, 70, 9651-9653.
DOI: 10.1021/jo051561h
Abstract
A mild and efficient Pd(II)-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated carbonyl compounds, aldehydes, esters, and amides in the presence of 2,2'-bipyridine was developed. The mechanism and the role of the bipyridine are discussed.
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Key Words
ID: J42-Y2005-1990
