Self-Assembled Bidentate Ligands for Ru-Catalyzed anti-Markovnikov Hydration of Terminal Alkynes
Floris Chevallier, Bernhard Breit*
*Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universität
Freiburg, Albertstrasse 21, 79104 Freiburg, Germany, Email: bernhard.breit
orgmail.chemie.uni-freiburg.de
F. Chevallier, B. Breit, Angew. Chem. Int. Ed., 2006, 45, 1599-1602.
DOI: 10.1002/anie.200503826
Abstract
A ruthenium catalyst was identified, which allows highly regioselective anti-Markovnikov hydration of terminal alkynes compatible with a wide range of functional groups.
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Key Words
aldehydes, alkynes, homogeneous catalysis, hydrogen bonding, ruthenium, self-assembly
ID: J06-Y2006-560
