Organic Chemistry Portal

Abstracts

Search:

Pd(0)-Catalyzed PMHS Reductions of Aromatic Acid Chlorides to Aldehydes

Kyoungsoo Lee and Robert E. Maleczka, Jr.*

*Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, Email: maleczkachemistry.msu.edu

K. Lee, R. E. Maleczka, Jr., Org. Lett., 2006, 8, 1887-1888.

DOI: 10.1021/ol060463v (free Supporting Information)


Abstract

Polymethylhydrosiloxane (PMHS) under Pd(0) catalysis can efficiently reduce aryl acid chlorides to their corresponding aldehydes in the presence of fluoride without requiring an additional reductant.

see article for more reactions



Key Words

Reduction of Acid Chlorides, PMHS


ID: J54-Y2006-1150