A Simple and Efficient Iron-Catalyzed Intramolecular Hydroamination of Unactivated Olefins
Kimihiro Komeyama, Takayuki Morimoto, Ken Takaki*
*Department of Chemistry and Chemical Engineering, Graduate School of
Engineering, Hiroshima University, Kagamiyama, Higashi-Hiroshima 739-8527, Japan, Email:
ktakaki
hiroshima-u.ac.jp
K. Komeyama, T. Morimoto, K. Takaki, Angew. Chem. Int. Ed., 2006, 45, 2938-2941.
DOI: 10.1002/anie.200503789 (free Supporting Information)
Abstract
A simple iron-catalyzed intramolecular hydroamination of unactivated olefins proceeds under mild conditions and tolerates aminoolefins containing halide moieties.
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Key Words
alkenes, homogeneous catalysis, hydroamination, iron, nitrogen heterocycles, pyrrolidines
ID: J06-Y2006-1160
