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Palladium(II)-Catalyzed Intramolecular Diamination of Unfunctionalized Alkenes

Jan Streuff, Claas H. Hövelmann, Martin Nieger and Kilian Muñiz*

*Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, D-53121 Bonn, Germany, Email: kilian.munizuni-bonn.de

J. Streuff, C. H. Hövelmann, M. Nieger, K. Muniz, J. Am. Chem. Soc., 2005, 127, 14586-14587.

DOI: 10.1021/ja055190y (free Supporting Information)


Abstract

A palladium-catalyzed intramolecular diamination reaction yields cyclic ureas as direct products of an oxidative alkene transformation in the presence of iodosobenzene diacetate as terminal oxidant.

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Key Words

Imidazolidones, Cyclic Urea Compounds, Diamination, Iodosobenzene Diacetate


ID: J48-Y2005-2730