Enantioselective Rh-Catalyzed Arylation of N-Tosylarylimines with Arylboronic Acids
Hai-Feng Duan, Yi-Xia Jia, Li-Xin Wang and Qi-Lin Zhou*
*State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai
University, Tianjin 300071, China, Email: qlzhou
nankai.edu.cn
H.-F. Duan, Y.-X. Jia, L-X. Wang, Q.-L. Zhou, Org. Lett., 2006, 8, 2567-2569.
DOI: 10.1021/ol060755w (free Supporting Information)
Abstract
The asymmetric arylation of N-tosylarylimines with arylboronic acids was realized by using rhodium/(S)-ShiP as catalyst in aqueous toluene to give diarylmethylamines in good yields and enantioselectivities.
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Key Words
diarylmethylamines, arylboronic acids, asymmetric catalysis
ID: J54-Y2006-1830
