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Synthesis of Bulky and Electron-Rich MOP-type Ligands and Their Applications in Palladium-Catalyzed C-N Bond Formation

Xiaomin Xie, Tony Y. Zhang and Zhaoguo Zhang*

*School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, 800 Dongchuan Road, Shanghai 200240, China, Email: zhaoguosjtu.edu.cn

X. Xie, T. Y. Zhang, Z. Zhang, J. Org. Chem., 2006, 71, 6522-6529.

DOI: 10.1021/jo060945k (free Supporting Information)


Abstract

Application of air and moisture stable 2-dialkylphosphino-2'-alkoxy-1,1'-binaphthyl ligands in palladium-catalyzed C-N bond forming reactions revealed the crucial roles of the steric bulk of the substituents on the phosphorus atom governing the catalytic activity.


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Key Words

Buchwald-Hartwig Coupling


ID: J42-Y2006-2590