A Sulfitylation-Oxidation Protocol for the Preparation of Sulfates
M. Huibers, lvaro Manuzi, Floris P. J. T. Rutjes and Floris L. van Delft*
*Institute for Molecules and Materials, Organic Chemistry, Radboud
University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, Email:
f.vandelft
science.ru.nl
M. Huibers, I. Manuzi, F. P. J. T. Rutjes, F. L. van Delft, J. Org. Chem., 2006, 71, 7473-7476.
DOI: 10.1021/jo060404v
Abstract
A novel, high-yielding method for sulfation of alcohols proceeds via sulfite- and sulfate diester intermediates. Sulfite diesters serve as versatile sulfate monoester precursors, that allow interesting transformations.
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Key Words
Sulfitylation, Sulfates, Ruthenium, Sodium Periodate
ID: J42-Y2006-2960
