A Simple and Efficient Method for Regioselective and Stereoselective Synthesis of Vicinal Bromohydrins and Alkoxybromides from an Olefin
Prodeep Phukan,* Pranita Chakraborty and Dolly Kataki
*Department of Chemistry, Gauhati University, Guwahati 781014, Assam, India, Email: pphukanyahoo.com
P. Phukan, P. Chakraborty, D. Kataki, J. Org. Chem., 2006, 71, 7533-7537.
DOI: 10.1021/jo0600611
Abstract
A very rapid and efficient method has been developed for the synthesis of vicinal bromohydrins and alkoxybromides directly from olefins without any catalyst using N,N-dibromo-p-toluenesulfonamide (TsNBr2) as the brominating agent in CH3CN-water or alcohol.
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Key Words
1,2-bromohydrins, 1,2-alkoxybromides
ID: J42-Y2006-2990