Regioselective Iron-Catalyzed Allylic Amination
Bernd Plietker
*Institut für Organische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany, Email: bernd.plietkeroc.uni-stuttgart.de
B. Plietker, Angew. Chem. Int. Ed., 2006, 45, 6053-6056.
DOI: 10.1002/anie.200602261
Abstract
Various allyl carbonates have been converted under Fe catalysis into essentially regio- and stereoisomerically pure allyl amines. Catalytic amounts of piperidinium hydrochloride as a buffer retard catalyst decomposition.
see article for more examples
A Highly Regioselective Salt-Free Iron-Catalyzed Allylic Alkylation
B. Plietker, Angew. Chem. Int. Ed., 2006, 45, 1469-1473.
Key Words
allylic amination, arylamines, homogeneous catalysis, iron, regioselectivity
ID: J06-Y2006-3030