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2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents

Alexey Y. Koposov, Rashad R. Karimov, Ivan M. Geraskin, Victor N. Nemykin* and Viktor V. Zhdankin*

*Department of Chemistry and Biochemistry, University of Minnesota-Duluth, Duluth, Minnesota 55812, Email: vzhdankid.umn.edu, vnemykind.umn.edu

A. Y. Koposov, R. R. Karimov, I. M. Geraskin, V. N. Nemykin, V. V. Zhdankin, J. Org. Chem., 2006, 71, 8452-8458.

DOI: 10.1021/jo0614947 (free Supporting Information)


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Abstract

Stable, microcrystalline 2-iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenol ethers. 2-Iodylphenol ethers can selectively oxidize sulfides to sulfoxides and alcohols to the respective aldehydes or ketones.

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RuCl3-Catalyzed Oxidation of Iodoarenes with Peracetic Acid: New Facile Preparation of Iodylarenes

A. Y. Koposov, R. R. Karimov, A. A. Pronin, T. Skrupskaya, M. S. Yusubov, V. V. Zhdankin, J. Org. Chem., 2006, 71, 9912-9914.


Key Words

Hypervalent Iodine(V) Compounds (Synthesis), Hypervalent Iodine Compounds (Reactions), Sulfoxides, Dimethyldioxirane


ID: J42-Y2006-3390