Developments in Pd Catalysis: Synthesis of 1H-1,2,3-Triazoles from Sodium Azide and Alkenyl Bromides
José Barluenga*, Carlos Valdés, Gustavo Beltrán, María Escribano, Fernando Aznar
*Instituto Universitario de Química Organometálica, Enrique Moles, Unidad
Asociada al CSIC, Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain, Email:
barluenga
uniovi.es
J. Barluenga, C. Valdés, G. Beltrán, M. Escribano, F. Aznar, Angew. Chem. Int. Ed., 2006, 45, 6893-6896.
DOI: 10.1002/anie.200601045
Abstract
A Pd-catalyzed synthesis of 1H-triazoles from alkenyl halides and sodium azide represents a completely new reactivity pattern in the context of Pd chemistry.
see article for more examples
Key Words
amination, azides, heterocycles, palladium catalysis, triazoles
ID: J06-Y2006-3410
