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Developments in Pd Catalysis: Synthesis of 1H-1,2,3-Triazoles from Sodium Azide and Alkenyl Bromides

José Barluenga*, Carlos Valdés, Gustavo Beltrán, María Escribano, Fernando Aznar

*Instituto Universitario de Química Organometálica, Enrique Moles, Unidad Asociada al CSIC, Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain, Email: barluengauniovi.es

J. Barluenga, C. Valdés, G. Beltrán, M. Escribano, F. Aznar, Angew. Chem. Int. Ed., 2006, 45, 6893-6896.

DOI: 10.1002/anie.200601045 (free Supporting Information)


Abstract

A Pd-catalyzed synthesis of 1H-triazoles from alkenyl halides and sodium azide represents a completely new reactivity pattern in the context of Pd chemistry.

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Key Words

amination, azides, heterocycles, palladium catalysis, triazoles


ID: J06-Y2006-3410