Aryl Sulfoxides via Palladium-Catalyzed Arylation of Sulfenate Anions
Guillaume Maitro, Sophie Vogel, Guillaume Prestat, David Madec* and Giovanni Poli*
*Université Pierre et Marie Curie-Paris 6, Laboratoire de Chimie Organique (UMR
CNRS 7611), Institut de Chimie Moléculaire (FR 2769), Case 183, 4 Place Jussieu,
F-75252, Paris Cedex 05, France, Email: giovanni.poli
upmc.fr,
david.madecupmc.fr
G. Maitro, S. Vogel, G. Prestat, D. Madec, G. Poli, Org. Lett., 2006, 8, 5951-5954.
DOI: 10.1021/ol062315a (free Supporting Information)
Abstract
A palladium-catalyzed arylation of sulfenate anions generated from β-sulfinyl esters takes place under basic biphasic conditions. This reaction provides a simple, mild, and efficient route to aryl sulfoxides in good yields.
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reaction pathway
Key Words
ID: J54-Y2006-4060
