C₃-Symmetric Ti(IV) Triphenolate Amino Complexes as Sulfoxidation Catalysts with Aqueous Hydrogen Peroxide

Myriam Mba, Leonard J. Prins and Giulia Licini*

*Università di Padova, Dipartimento di Scienze Chimiche, via Marzolo 1, 35131, Padova, Italy, Email: giulia.liciniunipd.it

M. Mba, L. J. Prins, G. Licini, Org. Lett., 2007, 9, 21-24.

DOI: 10.1021/ol062395i

---

Abstract

An air and moisture tolerant complex of Ti(IV) with a C₃-symmetric triphenolate amine ligand efficiently catalyzes sulfoxidation reactions at room temperature without previous activation using aqueous hydrogen peroxide as oxidant.

see article for more examples

---

---

Key Words

Sulfoxides, Hydrogen Peroxide

---

ID: J54-Y2007-0050