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Catalytic Oxidation of Imines Based on Methyltrioxorhenium/Urea Hydrogen Peroxide: A Mild and Easy Chemo- and Regioselective Entry to Nitrones

Gianluca Soldaini, Francesca Cardona and Andrea Goti*

*Dipartimento di Chimica Organica "Ugo Schiff", Laboratorio di Progettazione, Sintesi e Studio di Eterocicli Biologicamente Attivi (HeteroBioLab) and Consorzio INSTM, UniversitÓ di Firenze, via della Lastruccia 13, I-50019 Sesto Fiorentino (Firenze), Italy, Email: andrea.gotiunifi.it

G. Soldaini, F. Cardona, A. Goti, Org. Lett., 2007, 9, 473-476.

DOI: 10.1021/ol062862w (free Supporting Information)


Abstract

A general, high yielding, and user and environmentally friendly catalytic oxidation procedure for the chemoselective conversion of imines to nitrones is reported.

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Key Words

Nitrones, UHP, MTO


ID: J54-Y2007-0400