Nickel-Catalyzed Regio- and Stereoselective Silylation of Terminal Alkenes with Silacyclobutanes: Facile Access to Vinylsilanes from Alkenes
Koji Hirano, Hideki Yorimitsu and Koichiro Oshima*
*Department of Material Chemistry, Graduate School of Engineering, Kyoto
University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Email:
oshima
orgrxn.mbox.media.kyoto-u.ac.jp
K. Hirano, H. Yorimitsu, K. Oshima, J. Am. Chem. Soc., 2007, 129, 6094-6095.
DOI: 10.1021/ja070938t (free Supporting Information)
Abstract
The nickel-catalyzed reaction of terminal alkenes with silacyclobutanes afforded the corresponding vinylsilanes in a highly regio- and stereoselective fashion. The reaction provides a facile access to vinylsilanes starting from trivial terminal alkenes as well as styrenes, 1,3-dienes, and acrylate esters.
see article for more examples
Key Words
ID: J48-Y2007-1680
