The Surfactant-Promoted Cross-Coupling Reactions of Arylboronic Acids with Carboxylic Anhydrides or Acyl Chlorides in Water
Bingwei Xin, Yuhong Zhang*, Kai Cheng
*Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China, Email: yhzhangzjuem.zju.edu.cn
B. Xin, Y. Zhang, K. Cheng, Synthesis, 2007, 1970-1978.
DOI: 10.1055/s-2007-983729
Abstract
A palladium(II) chloride catalyzed mild cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides in water in the presence of the inexpensive surfactant sodium dodecyl sulfate (SDS) gives aryl ketones in good yields without the use of phosphine ligands.
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B. Xin, Yuhong Zhang, K. Cheng, J. Org. Chem., 2006, 71, 5725-5731.
Key Words
Green Chemistry, Aryl Ketones, Boronic Acids, Carboxylic Anhydrides, Acyl Chlorides, Palladium Catalysis
ID: J66-Y2007-2140