Scandium Triflate Catalyzed Aminolysis of meso-Aziridines

Saravanan Peruncheralathan, Michael Henze, Christoph Schneider*

*Institut für Organische Chemie, Universität Leipzig, Johannisallee 29, 04103 Leipzig, Germany, Email: schneiderchemie.uni-leipzig.de

S. Peruncheralathan, M. Henze, C. Schneider, Synlett, 2007, 2289-2291.

DOI: 10.1055/s-2007-984920

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Abstract

The aminolysis of meso-N-phenyl aziridines is efficiently catalyzed by 1 mol% of Sc(OTf)₃ and furnishes valuable 1,2-diamines in good to excellent yields.

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Key Words

amines, aziridines, 1,2-diamines, catalysis, scandium

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ID: J60-Y2007-3030