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Waste-Free and Environment-Friendly Uncatalyzed Synthesis of Dithiocarbamates under Solvent-Free Conditions

Najmedin Azizi, Forogh Ebrahimi, Elham Aakbari, Fezzeh Aryanasab, Mohammad R. Saidi*

*Department of Chemistry, Sharif University of Technology, P. O. Box 11465-9516, Tehran 11365, Email: saidisharif.edu

N. Azizi, F. Ebrahimi, E. Aakbari, F. Aryanasab, M. R. Saidi, Synlett, 2007, 2797-2800.

DOI: 10.1055/s-2007-991085


Abstract

A mild, convenient, and practical one-pot procedure gives dithiocarbamates in good to excellent yields by condensation of amines, CS2, and a Michael acceptor, under solvent-free conditions at room temperature.


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Straightforward and Highly Efficient Catalyst-Free One-Pot Synthesis of Dithiocarbamates under Solvent-Free Conditions

N. Azizi, F. Aryanasab, M. R. Saidi, Org. Lett., 2006, 8, 5275-5277.


Key Words

Dithiocarbamates, Amination, Green Chemistry, Multicomponent Reactions


ID: J60-Y2007-3580