Cu(I)-Catalyzed Intermolecular Diamination of Activated Terminal Olefins
Baoguo Zhao, Weicheng Yuan, Haifeng Du and Yian Shi*
*Department of Chemistry, Colorado State University, Fort
Collins, Colorado 80523, Email: yian
lamar.colostate.edu
B. Zhao, W. Yuan, H. Du, Y. Shi, Org. Lett., 2007, 9, 4943-4945.
DOI: 10.1021/ol702061s (free Supporting Information)
Abstract
The use of CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source allows an effective diamination of activated terminal olefins in good yields under mild reaction conditions.
see article for more examples
Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways
B. Zhao, X. Peng, S. Cui, Y. Shi, J. Am. Chem. Soc., 2010, 132, 11009-11011.
Key Words
ID: J54-Y2007-3670
