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Stereoselective RhI-Catalyzed Tandem Conjugate Addition of Boronic Acids−Michael Cyclization

Cristina Navarro and Aurelio G. Csák˙*

*Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040-Madrid, Spain, Email: csakyquim.ucm.es

C. Navarro, A. G. Csák˙, Org. Lett., 2008, 10, 217-219.

DOI: 10.1021/ol702571c (free Supporting Information)


Abstract

A stereoselective sequence of a RhI-catalyzed conjugate addition of boronic acids to enones followed by a Michael cyclization gives 1,2,3-trisubstituted indans in a highly regio- and stereoselective fashion.

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Key Words

Indanes


ID: J54-Y2008-0130