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Rhodium-Catalyzed One-Pot Synthesis of Substituted Pyridine Derivatives from α,β-Unsaturated Ketoximes and Alkynes

Kanniyappan Parthasarathy, Masilamani Jeganmohan and Chien-Hong Cheng*

*Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan, Email: chchengmx.nthu.edu.tw

K. Parthasararathy, M. Jeganmohan, C.-H. Cheng, Org. Lett., 2008, 10, 325-328.

DOI: 10.1021/ol7028367 (free Supporting Information)


Abstract

A rhodium-catalyzed chelation-assisted C-H activation of α,β-unsaturated ketoximes and the reaction with alkynes affords highly substituted pyridine derivatives.

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Key Words

Pyridines


ID: J54-Y2008-0240