Methoxide Ion Promoted Efficient Synthesis of 1,3-Oxathiolane-2-thiones by Reaction of Oxiranes and Carbon Disulfide
Issa Yavari*, Majid Ghazanfarpour-Darjani, Zinatossadat Hossaini, Maryam Sabbaghan, Nargess Hosseini
*Chemistry Department, Tarbiat Modares University, PO Box
14115-175, Tehran, Iran,
Email: yavarisa
modares.ac.ir
I. Yavari, M. Ghazanfarpour-Darjani, Z. Hossaini, M. Sabbaghan, N. Hosseini, Synlett, 2008, 889-891.
DOI: 10.1055/s-2008-1042927
Abstract
An efficient reaction of carbon disulfide with oxiranes in the presence of sodium hydride (10 mol%) and methanol gives functionalized 1,3oxathiolane-2-thiones in very good yields.
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Key Words
oxathiolane, oxiranes, carbon disulfide, methoxide ion, S-heterocycles
ID: J60-Y2008-0900
