Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors
Verena T. Trepohl, Susumu Mori, Kenichiro Itami and Martin Oestreich*
*Organisch-Chemisches Institut, Westflische
Wilhelms-Universitt, Corrensstrasse 40, D-48149 Münster, Germany, and Department
of Chemistry, Email: martin.oestreich
tu-berlin.de
V. T. Trepohl, S. Mori, K. Itami, M. Oestreich, Org. Lett., 2009, 11, 1091-1094.
DOI: 10.1021/ol8028466
Abstract
Several E and Z configured α,β-unsaturated carbonyl and carboxyl acceptors (including imides) as well as nitroalkenes participate in a palladium(II)-catalyzed conjugate transfer of diphenyl-, dicyclohexyl-, and di-tert-butylphosphinyl groups from silylphosphines in high chemical yields.
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Key Words
ID: J54-Y2009-0700
