Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways
Baoguo Zhao, Xingao Peng, Sunliang Cui and Yian Shi*
*Department of Chemistry, Colorado State University, Fort
Collins, Colorado 80523, Email: yian
lamar.colostate.edu
B. Zhao, X. Peng, S. Cui, Y. Shi, J. Am. Chem. Soc., 2010, 132, 11009-11011.
DOI: 10.1021/ja103838d
Abstract
Cu(I)-catalyzed diamination of conjugated dienes with di-tert-butyldiaziridinone as nitrogen source proceeds at the internal double bond with high regio- and diasteroselectivity in good yield using inexpensive CuBr as catalyst.
see article for more examples
Diamination of Conjugated Dienes and Trienes Catalyzed by N-Heterocyclic Carbene-Pd(0) Complexes
L. Xu, H. Du, Y. Shi, J. Org. Chem., 2007, 72, 7038-7041.
Cu(I)-Catalyzed Intermolecular Diamination of Activated Terminal Olefins
B. Zhao, W. Yuan, H. Du, Y. Shi, Org. Lett., 2007, 9, 4943-4945.
Key Words
ID: J48-Y2010-2250
