Organic Chemistry Portal

Abstracts

Search:

[Me2C(C5H4)2TiMe2]: An Open-Bent Titanocene Catalyst for the Hydrosilylation of Bulky 1,3-Dienes

Roxana Pop, Jin Lan Cui, Louis Adriaenssens, Virginie Comte, Pierre Le Gendre*

*Institut de Chimie Moléculaire de l'Université de Bourgogne, ICMUB-UMR CNRS 5260, Université de Bourgogne, 9 Avenue Alain Savary, BP 47870, 21078 Dijon Cedex, France, Email: pierre.le-gendreu-bourgogne.fr

R. Pop, J. L. Cui, L. Adriaenssens, V. Comte, P. Le Gendre, Synlett, 2011, 679-683.

DOI: 10.1055/s-0030-1259687



see article for more reactions

Abstract

An open-bent titanocene complex [Me2C(C5H4)2TiMe2] proved to be efficient for the hydrosilylation of a variety of substrates such as disubstituted dienes, activated alkenes, and even an alkyne.

see article for more examples



Key Words

hydrosilylation, titanium, dienes, allylsilanes, homogeneous catalysis


ID: J60-Y2011-0760